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Microstructure effects on the energy storage density in BiFeO3-based ferroelectric ceramics
The poor comprehensive energy storage performance (energy storage density and energy storage efficiency) is a key scientific problem to be solved in the field of energy storage ceramics. In this work, (0.67-x)BiFeO 3-xBi 0.1 Na 0·7 NbO 3-0.33BaTiO 3-0.15 wt%MnCO 3 (BNBFNT-x, x = 0, 0.1, 0.2, and 0.3) ceramics were designed.
Dielectric and ferroelectric properties of SrTiO3-Bi0.54Na0.46TiO3-BaTiO3 lead-free ceramics for high energy storage
The need of lead-free ceramics with excellent dielectric behaviors and high energy storage properties have been extensively studied. In this study, (1-x)SrTiO 3-x(0.94Bi 0.54 Na 0.46 TiO 3-0.06BaTiO 3) ((1-x)ST-xBNBT) lead-free ceramics were designed and fabricated using the conventional solid state sintering method.
Structural, dielectric, and ferroelectric properties of BaTiO3–Bi(Ni1/2Ti1/2)O3 lead-free ceramics with remarkable energy storage
In order to fabricate high-performance dielectric capacitors for pulsed power applications, (1 − x)BaTiO3–xBi(Ni1/2Ti1/2)O3 [(1 − x)BT–xBNT] polycrystalline ceramics were prepared by solid-state reaction method. Profound structural tests by Raman spectrum and X-ray diffraction verified Ni2+ and Bi3+ partially substituted the Ti and Ba
Ferroelectric Materials for Energy Harvesting and Storage
This chapter broadly covers the studies on energy storage properties of lead-based and lead-free ferroelectric, relaxor ferroelectric, and antiferroelectric bulk ceramics and films. Employment of dielectric capacitors in pulsed power systems and their applications, figures of merit for energy storage performance, and the dielectric properties influencing them
[Bi3+/Zr4+] induced ferroelectric to relaxor phase transition of BaTiO3 ceramic for significant enhancement of energy storage
The low breakdown strength and recoverable energy storage density of pure BaTiO3 (BT) dielectric ceramics limits the increase in energy-storage density. This study presents an innovative strategy to improve the energy storage properties of BT by the addition of Bi2O3 and ZrO2. The effect of Bi, Mg and Zr ions (reviate BMZ) on the
A review on the development of lead-free ferroelectric energy
In this review, we comprehensively summarize the research progress of lead-free dielectric ceramics for energy storage, including ferroelectric ceramics, composite ceramics,
High energy storage density achieved in BNT‐based ferroelectric translucent ceramics
However, designing a material that can achieve high energy density under low electric fields remains a challenge. In this work, (1−x)Bi 0.5 Na 0.5 TiO 3 −xBaZr 0.3 Ti 0.7 O 3:0.6mol%Er 3+ (reviated as (1−x)BNT−xBZT:0.6%Er 3+) ferroelectric translucent
High energy storage density achieved in BNT‐based
The development of ceramics with superior energy storage performance and transparency holds the potential to broaden
Core–Shell Grain Structure and High Energy Storage Performance of BNT-Based Relaxor Ferroelectric Ceramics
Bismuth sodium titanate (Bi0.5Na0.5TiO3, BNT) based ferroelectric ceramic is one of the important lead free dielectric materials for high energy storage applications due to its large polarization. Herein, we reported a modified BNT based relaxor ferroelectric ceramics composited with relaxor Sr0.7Bi0.2TiO3 (SBT) and ferroelectric
A review on the development of lead-free ferroelectric energy-storage ceramics and multilayer capacitors
Energy storage materials and their applications have attracted attention among both academic and industrial communities. Over the past few decades, extensive efforts have been put on the development of lead-free high-performance dielectric capacitors. In this review, we comprehensively summarize the research
Ferroelectric Glass-Ceramic Systems for Energy
An overview of ferroelectric glass ceramics, some literature review and some of the important previous studies were focused in this chapter. Nanocrystalline glass–ceramics containing ferroelectric
Innovative perspectives on porous ferroelectric ceramics and their composites: Charting new frontiers in energy
Regarding ferroelectric properties, PFMs exhibit heightened ionic conductivity and reduced polarization fatigue, leading to enhanced energy storage capabilities. The unique microstructure also contributes to improved piezoelectric performance, and the increased surface area boosts pyroelectric response, making PFMs
Combinatorial optimization of perovskites-based ferroelectric
In this Review, we outline the recent development of perovskite-based ferroelectric energy storage ceramics from the perspective of combinatorial optimization for tailoring
Optimizing dielectric energy storage properties of BNT-based relaxor ferroelectric ceramics
Low-voltage driven ceramic capacitor applications call for relaxor ferroelectric ceramics with superior dielectric energy storage capabilities. Here, the (Bi0.5Na0.5)0.65(Ba0.3Sr0.7)0.35(Ti0.98Ce0.02)O3 + x wt% Ba0.4Sr0.6TiO3 (BNBSTC + xBST, x = 0, 2, 4, 6, 8, 10) ceramics were prepared to systematically investigate the
High thermal stability in PLZST anti-ferroelectric energy storage ceramics with the coexistence of tetragonal and orthorhombic
The orthorhombic phase Pb 0.97 La 0.02 (Zr 0.93 Sn 0.05 Ti 0.02)O 3 (PLZST) and the tetragonal phase (Pb 0.93 Ba 0.04 La 0.02)(Zr 0.65 Sn 0.3 Ti 0.05)O 3 (PBLZST) were composited by the conventional solid state method to acquire high energy storage density and high thermal stability.
Microstructure effects on the energy storage density in BiFeO3-based ferroelectric ceramics
Based on the microstructure, electrical analysis and domain configuration of the considered ceramics, Novel BiFeO 3-BaTiO 3-Ba(Mg 1/3 Nb 2/3)O 3 lead-free relaxor ferroelectric ceramics for energy-storage capacitors J. Am. Ceram. Soc., 98
Energy storage performance of Na0.5Bi0.5TiO3 based lead-free ferroelectric ceramics prepared
Generally, typical ferroelectric ceramics typically have a large P max in the same applied electrical field, which is very helpful in achieving a high energy storage density [38], [39]. However most of the ferroelectric macro domains cannot be restored to their initial stage once the electrical field has been removed, leaving a big P r, which is
The effects of R2O3 (R=La, Yb, Gd) on the microstructure, dielectric, ferroelectric, and energy storage
The effects of R 2 O 3 (R=La, Yb, Gd) on the microstructure, dielectric, ferroelectric, and energy storage properties of Ba 0.65 Bi 0.07 Sr 0.245 TiO 3 relaxor ferroelectric ceramics Author links open overlay panel Fukang Chen a, Yilin Zhang a, Yang Li b, Yan Yan a, Lishun Yang a, Xinyu Zeng a, Tao Deng a, Huanghui Nie a,
Regulating the Structural, Transmittance, Ferroelectric, and Energy Storage Properties of K0.5Na0.5NbO3 Ceramics
Lead-free (1 − x)K0.5Na0.5NbO3–xSr(Yb0.5Nb0.5)O3 (KNN–xSYbN, x = 0.15, 0.175, 0.20, 0.225, 0.25, 0.30) ceramics have been fabricated using the traditional solid-phase sintering method. The effects of Sr(Yb0.5Nb0.5)O3 doping on the microstructure, phase transition, and optical and electrical properties were investigated in
Optimization of energy-storage properties for lead-free relaxor
In this work, the excellent energy-storage properties are achieved in (1-x)Na0.5Bi0.5TiO3-xSr0.7Nd0.2TiO3 ((1-x)NBT-xSNT) ferroelectric ceramics by a
Progress and perspectives in dielectric energy storage ceramics
<p>Dielectric ceramic capacitors, with the advantages of high power density, fast charge- discharge capability, excellent fatigue endurance, and good high temperature stability, have been acknowledged to be promising candidates for solid-state pulse power systems. This review investigates the energy storage performances of linear dielectric, relaxor
An energy-based model for ferroelectric ceramics
An energy-based model to describe the behaviour of ferroelectric ceramics is proposed in this paper. The model relies on two constitutive functions: The free energy and the dissipation. The dissipation is generated by the pinning of the walls while the free energy is defined using a simplified formulation of a multi-scale model.
A review on the development of lead-free ferroelectric energy
In this review, we comprehensively summarize the research progress of lead-free dielectric ceramics for energy storage, including ferroelectric ceramics,
Multi-scale domain and microstructure engineering for the high-energy-storage BCZT based lead-free relaxor ferroelectric ceramics
Fulfilling the stringent demand of the miniature and eco-friendly pulsed power devices, development of high-energy-storage lead-free dielectric energy storage is critical. To achieve this goal, the mature strategy is to induce the formation of relaxor polar nano regions (PNRs) by means of constructing multiple solid solutions and element
An automatically curated first-principles database of ferroelectrics
Our code for the DFT and polarization analysis workflows for performing polarization calculations has been contributed to atomate under the
A Review on Lead-Free-Bi0.5Na0.5TiO3 Based Ceramics and Films: Dielectric, Piezoelectric, Ferroelectric and Energy Storage
Among the currently reported relaxor ferroelectric materials, ceramics based on Na 0.5 Bi 0.5 TiO 3 (NBT) are considered the most competitive lead-free energy storage ceramics because of their
Enhanced optical and energy storage properties of K0.5Na0.5NbO3 lead-free ceramics
The energy storage densities of ceramics are presented in Fig. 5 b, where the highest energy storage density is 4.13 J/cm 3. With the increase of BSZ content, the effective energy storage density increases and then decreases, and at x = 0.125, the highest effective energy storage density of 2.95 J/cm 3 is obtained.
Toward Design Rules for Multilayer Ferroelectric Energy Storage Capacitors – A Study Based on Lead‐Free and Relaxor‐Ferroelectric
Here, a study of multilayer structures, combining paraelectric-like Ba 0.6 Sr 0.4 TiO 3 (BST) with relaxor-ferroelectric BaZr 0.4 Ti 0.6 O 3 (BZT) layers on SrTiO 3-buffered Si substrates, with the goal to optimize the
Significantly enhanced dielectric breakdown strength of
This work demonstrates that significant enhancement in dielectric breakdown strength of ferroelectric energy-storage ceramics can be achieved via grain
High-entropy relaxor ferroelectric ceramics for ultrahigh energy
This study provides evidence that developing high-entropy relaxor ferroelectric material via equimolar-ratio element design is an effective strategy for achieving ultrahigh energy storage
An automatically curated first-principles database of ferroelectrics
Our automated workflow has three stages: symmetry analysis, first-principles calculations, and post-processing. Accordingly, the rest of the work is organized as follows: the description of the